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Organic Chemistry A Brief Course International Edition 13th Edition – Test Bank

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Organic Chemistry A Brief Course International Edition 13th Edition by David J. Hart – Test Bank

Chapter 5 — Stereoisomerism

MULTIPLE CHOICE

1. Which of the following objects is chiral?

A)

egg

B)

pencil

C)

cross country skis

D)

paperclip

E)

shoes

ANS: E TOP: Definitions

2. Chiral molecules that have non-superimposable mirror images are called:

A)

enantiomers

B)

diastereomers

C)

Meso compounds

D)

stereogenic

E)

symmetrical

ANS: A TOP: Definitions

3. Which of the following molecules has a mirror plane of symmetry?

            

A)

1

B)

2

C)

3

D)

4

E)

all of them

ANS: B TOP: Definitions

4. What is the process that separates enantiomers?

A)

separation

B)

decoupling

C)

resetting

D)

resolution

E)

selective binding

ANS: D TOP: Definitions

5. A 50:50 mixture of enantiomers

A)

is a meso form.

B)

is a pair of diastereomers.

C)

is a racemic mixture.

D)

rotates plane-polarized light.

E)

is a pair of conformers.

ANS: C TOP: Definitions

6. The terms that best describe the isomeric relationship between staggered and eclipsed ethane are

A)

configurational, achiral, diastereomers.

B)

conformational, chiral, enantiomers.

C)

conformational, achiral, diastereomers.

D)

configurational, chiral, enantiomers.

E)

conformational, achiral, enantiomers.

ANS: C TOP: Definitions

7. Which of the molecules below has a stereogenic carbon atom?

                 

A)

1

B)

2

C)

3

D)

2 and 3

E)

1, 2, and 3

ANS: B TOP: Definitions

8. How many stereogenic centers are present in the following molecule?

                                    

                                               

A)

1

B)

2

C)

3

D)

4

E)

5

ANS: B TOP: Definitions

9. How many stereogenic centers are present in the following molecule?

                                                 

A)

1

B)

2

C)

4

D)

6

E)

8

ANS: B TOP: Definitions

10. How many chiral stereoisomers can be drawn for CH3CHClCHBrCH3?

A)

1

B)

2

C)

3

D)

4

E)

8

ANS: D TOP: Definitions

11. How many stereogenic carbons are in the following molecule?

                                                

A)

0

B)

1

C)

2

D)

3

E)

4

ANS: A TOP: Definitions

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